: The aims of this research are to describe: (1) the structures from Tere Liye's novel Pukat; (2) the values of character education contained in the Tere Liye's novel Pukat; (3) the relevance of structural analysis and the value of character education from Tere Liye's novel Pukat towards Indonesian language learning materials in Senior High School.This research is a qualitative descriptive study with content analysis method. Based on the results of the study in chapter 4 can be summarized as follows: (1) Structural analysis; the theme of the novel Pukat is the simplicity of life, honesty, and compassion. The story line used is a mixture storyline. Characterizations in the novel Pukat divided into the main character and an additional character. Viewing angles are used is a first person perspective as the main character. Background used is background of the place, time setting, and social background. The dominant style of language used is metaphor, personification, simile, and hyperbole. Message that used expressed on the content of the novel; (2) The educational value of the characters in the novel are social care, discipline, hard work, creativity, curiousity, communicative, likes to read, religious, honesty, independent, caring for the environment, and responsibility; (3) Based on the structural analysis and the value of character education as well as the results of interviews conducted by teachers and students, it can be seen that a novel Pukat has a characteristic of the good learning materials. Because of that, this novel suitability of Indonesian language learning materials in Senior High School.